Exchange Coupling in Synthetic Anion‐Engineered Chromia Heterostructures

نویسندگان

چکیده

Control of magnetic states by external factors has garnered a mainstream status in spintronic research for designing low power consumption and fast-response information storage processing devices. Previously, magnetic-cation substitution is the conventional means to induce ferromagnetism an intrinsic antiferromagnet. Theoretically, anion-doping proposed be another effect change ground states. Here we demonstrate synthesis high-quality single-phase chromium oxynitride thin films using in-situ nitrogen doping. Unlike antiferromagnetic monoanionic oxide nitride phases, exhibits robust ferromagnetic insulating state, as demonstrated combination multiple magnetization probes theoretical calculations. With increasing content, crystal structure transits from trigonal (R3c) tetragonal (4mm) phase its saturation reduces significantly. Furthermore, achieve large controllable exchange bias field chromia heterostructures synthetic anion engineering. This work reflects engineering functional oxides towards potential applications giant magnetoresistance tunnelling junctions modern sensors read heads.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2021

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202109828